Remarkable O-2-effect in 1,4-additions of diethylzinc to 6- acyloxy-2H-pyran-3(6H)-ones and 6-alkoxy-2H-pyran-3(6H)-ones

Authors :: Rm Kellogg
H. Van Der Deen
Bernard Feringa
Faculty of Science and Engineering
Synthetische Organische Chemie
Stratingh Institute of Chemistry
Moleculaire Anorganische Chemie
Source :: Organic letters, 2(11), 1593-1595. AMER CHEMICAL SOC INC
Publication Year :: 2000
Publisher :: AMER CHEMICAL SOC INC, 2000.
Abstract: Under the influence of air, a facile 1,4-addition of diethylzinc to acyloxypyranones and alkoxypyranones 1 takes place. Reaction of diethylzinc with molecular oxygen provides EtOOZnEt, which cataly...

Subjects :: Chemistry
Organic Chemistry
chemistry.chemical_element
Diethylzinc
Biochemistry
Oxygen
OXYGEN
chemistry.chemical_compound
Pyran
Reagent
Alkoxy group
Organic chemistry
REAGENTS
Molecular oxygen
ENONES
Physical and Theoretical Chemistry
CONJUGATE ADDITION
ASYMMETRIC EPOXIDATION

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