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A novel 3-D cuprous iodide polymer with a high Cu/I ratio
- Source :
- Dalton Transactions. 47:3253-3257
- Publication Year :
- 2018
- Publisher :
- Royal Society of Chemistry (RSC), 2018.
-
Abstract
- A novel 3-D cuprous iodide polymer [CuI3I(μ6-L)]n with a Cu/I ratio as high as 3 (1, H2L = 1,3-bis(2H-tetrazol-5-yl)benzene) has been hydrothermally synthesized. The 3-D framework of 1 is constructed by the linkages of rare 1-D cationic aggregates [CuI3I2+]n and anionic bi-tetrazolate bridges. 1 shows unusually thermochromic luminescent and photocatalytic properties, and its density functional theory calculation has also been studied.
- Subjects :
- chemistry.chemical_classification
Thermochromism
Materials science
010405 organic chemistry
Iodide
Cationic polymerization
Polymer
010402 general chemistry
01 natural sciences
0104 chemical sciences
Inorganic Chemistry
chemistry.chemical_compound
chemistry
Polymer chemistry
Photocatalysis
Density functional theory
Benzene
Luminescence
Subjects
Details
- ISSN :
- 14779234 and 14779226
- Volume :
- 47
- Database :
- OpenAIRE
- Journal :
- Dalton Transactions
- Accession number :
- edsair.doi.dedup.....3731aae36554ac60f5141a38b79b8601