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Crystal design using multipolar electrostatic interactions: A concept study for organic electronics
- Source :
- Beilstein Journal of Organic Chemistry, Vol 9, Iss 1, Pp 2367-2373 (2013), Beilstein Journal of Organic Chemistry
- Publication Year :
- 2013
- Publisher :
- Beilstein-Institut, 2013.
-
Abstract
- Using a simple synthetic protocol, heterohexacene analogues with a quadrupolar distribution of partial charges are readily available. In contrast to most other acenes, these compounds crystallize with a slipped-stack, brickwork-like packing which is mainly controlled by electrostatic interactions. This type of packing offers an advantage for organic semiconductors, because it allows more isotropic charge transport compared to the “herring bone” stacking observed for other acenes.
- Subjects :
- Organic electronics
organo-fluorine
Chemistry
organic semiconductor
Isotropy
Organic Chemistry
Stacking
Charge (physics)
Nanotechnology
aromatic stacking
Electrostatics
Full Research Paper
Crystal
Organic semiconductor
lcsh:QD241-441
Partial charge
electrostatic control
lcsh:Organic chemistry
Chemical physics
charge carrier transport
crystal design
lcsh:Q
lcsh:Science
Subjects
Details
- Language :
- English
- ISSN :
- 18605397
- Volume :
- 9
- Issue :
- 1
- Database :
- OpenAIRE
- Journal :
- Beilstein Journal of Organic Chemistry
- Accession number :
- edsair.doi.dedup.....3be23d7807c3f92342a8510942dbb37e