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Development of a new Lindqvist-like Fe6 cluster secondary building unit for MOFs
- Source :
- Chemical communications (Cambridge, England). 55(72)
- Publication Year :
- 2019
-
Abstract
- This work demonstrates a new Lindqvist-like [FeIII6(μ6-O)L4Cl6]2- (Fe6, L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) cluster for the construction of a novel class of Fe-cluster organic frameworks. The novel Fe6 cluster can be used to build not only a homometallic MOF, but also a heterometallic MOF by introducing copper halide clusters to the reaction system. In particular, the heterometallic MOF achieved a skillful combination of Fe6 SBU and cuprous-halide clusters for the first time. Our synthesis strategy opens up an effective avenue to novel Fe-cluster-based MOF materials.
- Subjects :
- Secondary building unit
Materials science
010405 organic chemistry
Metals and Alloys
General Chemistry
010402 general chemistry
01 natural sciences
Combinatorial chemistry
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
chemistry
Materials Chemistry
Ceramics and Composites
Cluster (physics)
Hydroxymethyl
Reaction system
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 55
- Issue :
- 72
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....3c7b6eb93fdc7f26d6c5a6c036770d5e