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Redox-induced reversible P–P coupling in a uranium complex
- Source :
- Chemical Communications, Chemical Communications, 2021, 57 (91), pp.12175-12178. ⟨10.1039/d1cc04765e⟩
- Publication Year :
- 2021
- Publisher :
- Royal Society of Chemistry (RSC), 2021.
-
Abstract
- International audience; A synthesized redox-active multidentate N-P ligand reacted with UCl4 in the presence of KHMDS or (BuLi)-Bu-n, where two novel U(iv) complexes with or without P-P coupling were formed, respectively. The reversible P-P coupling in these complexes was observed in redox-induced reactions.
- Subjects :
- Denticity
Ligand
Metals and Alloys
chemistry.chemical_element
General Chemistry
Uranium
Redox
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Coupling (electronics)
Crystallography
chemistry
Materials Chemistry
Ceramics and Composites
[PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 57
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....3fb6404374f696d123d6ac9e6136bfb1
- Full Text :
- https://doi.org/10.1039/d1cc04765e