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Molecular Systems Combining Porphyrinoids and N‐Heterocyclic Carbenes
- Source :
- European Journal of Inorganic Chemistry, European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2021, 2021 (9), pp.776-791. ⟨10.1002/ejic.202001011⟩
- Publication Year :
- 2021
- Publisher :
- Wiley, 2021.
-
Abstract
- International audience; Porphyrins and N-heterocyclic carbenes (NHCs) are both relevant ligands in the fields of coordination and organometallic chemistry. Despite evident structural differences, porphyrins and NHCs have a lot in common such as their ability to form strong metalligand bonds and their use in catalysis, materials science and biomedicine. During the last decade, several molecular systems combining porphyrins and NHC ligands were reported in the literature. The present review gathers relevant examples where NHC ligands are either axially bonded to metalloporphyrins or covalently attached to the porphyrin cores. Structural diversity, electronic interplay between porphyrins and NHCs and some relevant applications in catalysis and biomedicine are notably described. Finally, molecular systems combining NHCs with other original porphyrinoids such as Nconfused porphyrins, subporphyrins and norcorroles are also presented.
- Subjects :
- [CHIM.ORGA]Chemical Sciences/Organic chemistry
010405 organic chemistry
Structural diversity
Molecular electronics
Homogeneous catalysis
[CHIM.CATA]Chemical Sciences/Catalysis
Molecular systems
010402 general chemistry
01 natural sciences
Combinatorial chemistry
Porphyrin
0104 chemical sciences
Catalysis
Inorganic Chemistry
chemistry.chemical_compound
chemistry
Covalent bond
[CHIM]Chemical Sciences
[CHIM.COOR]Chemical Sciences/Coordination chemistry
Organometallic chemistry
Subjects
Details
- ISSN :
- 10990682 and 14341948
- Volume :
- 2021
- Database :
- OpenAIRE
- Journal :
- European Journal of Inorganic Chemistry
- Accession number :
- edsair.doi.dedup.....40ee01a31d7480bf47e189098c7ce3c9