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Automated full-dimensional potential energy surface development and quasi-classical dynamics for the HI(X1Σ+) + C2H5 → I(2P3/2) + C2H6 reaction

Authors :
Cangtao Yin
Gábor Czakó
Source :
Physical Chemistry Chemical Physics. 24:29084-29091
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

We develop a high-level spin–orbit-corrected analytical ab initio potential energy surface and perform quasi-classical trajectory simulations to study the dynamics of the 9-atomic HI + C2H5 → I + C2H6 reaction in full (21) dimensions.

Details

ISSN :
14639084 and 14639076
Volume :
24
Database :
OpenAIRE
Journal :
Physical Chemistry Chemical Physics
Accession number :
edsair.doi.dedup.....4374eb055278c7b828c0bba6a167d325
Full Text :
https://doi.org/10.1039/d2cp04416a