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Stabilization and transfer of the transient [Mes*P4]‒ butterfly anion using BPh3
- Source :
- Borger, J E, Ehlers, A W, Lutz, M, Slootweg, J C & Lammertsma, K 2016, ' Stabilization and transfer of the transient [Mes*P4]‒ butterfly anion using BPh3 ', Angewandte Chemie International Edition in English, vol. 55, pp. 613-617 . https://doi.org/10.1002/anie.201508916, Angewandte Chemie International Edition in English, 55, 613-617. John Wiley and Sons Ltd, Angewandte Chemie-International Edition, 55(2), 613. John Wiley and Sons Ltd
- Publication Year :
- 2016
-
Abstract
- The transient bicyclo[1.1.0]tetraphosphabutane anion, generated from white phosphorus (P4 ) and Mes*Li (Mes*=2,4,6-tBu3 C6 H2 ), can be trapped by BPh3 in THF. This Lewis acid stabilized anion can be used as an [RP4 ](-) transfer agent, reacting cleanly with neutral Lewis acids (B(C6 F5 )3 , BH3 , and W(CO)5 ) to afford unique singly and doubly coordinated butterfly anions, and with the trityl cation to form a neutral, nonsymmetrical, all-carbon-substituted P4 derivative. This reaction path enables a simple, stepwise functionalization of white phosphorus.
- Subjects :
- Bicyclic molecule
010405 organic chemistry
White Phosphorus
boranes
Phosphorus
Inorganic chemistry
chemistry.chemical_element
Boranes
General Medicine
organophosphorus compounds
General Chemistry
Borane
010402 general chemistry
01 natural sciences
Medicinal chemistry
Catalysis
0104 chemical sciences
Ion
chemistry.chemical_compound
chemistry
Transfer agent
Lewis acids
Lewis acids and bases
phosphorus
anions
Subjects
Details
- ISSN :
- 05700833 and 14337851
- Database :
- OpenAIRE
- Journal :
- Borger, J E, Ehlers, A W, Lutz, M, Slootweg, J C & Lammertsma, K 2016, ' Stabilization and transfer of the transient [Mes*P4]‒ butterfly anion using BPh3 ', Angewandte Chemie International Edition in English, vol. 55, pp. 613-617 . https://doi.org/10.1002/anie.201508916, Angewandte Chemie International Edition in English, 55, 613-617. John Wiley and Sons Ltd, Angewandte Chemie-International Edition, 55(2), 613. John Wiley and Sons Ltd
- Accession number :
- edsair.doi.dedup.....49859b7fd0b0bbd791e5c59b3ef98197