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Remarkably enhanced dielectric stability and energy storage properties in BNT—BST relaxor ceramics by A-site defect engineering for pulsed power applications
- Source :
- Journal of Advanced Ceramics, Vol 11, Iss 2, Pp 283-294 (2022)
- Publication Year :
- 2022
- Publisher :
- SpringerOpen, 2022.
-
Abstract
- Lead-free bulk ceramics for advanced pulsed power capacitors show relatively low recoverable energy storage density (Wrec) especially at low electric field condition. To address this challenge, we propose an A-site defect engineering to optimize the electric polarization behavior by disrupting the orderly arrangement of A-site ions, in which $${\rm{B}}{{\rm{a}}_{0.105}}{\rm{N}}{{\rm{a}}_{0.325}}{\rm{S}}{{\rm{r}}_{0.245 - 1.5x}}{_{0.5x}}{\rm{B}}{{\rm{i}}_{0.325 + x}}{\rm{Ti}}{{\rm{O}}_3}$$ Ba 0.105 Na 0.325 Sr 0.245 − 1.5 x □ 0.5 x Bi 0.325 + x TiO 3 ($${\rm{BN}}{{\rm{S}}_{0.245 - 1.5x}}{_{0.5x}}{{\rm{B}}_{0.325 + x}}{\rm{T}}$$ BNS 0.245 − 1.5 x □ 0.5 x B 0.325 + x T , x = 0, 0.02, 0.04, 0.06, and 0.08) lead-free ceramics are selected as the representative. The $${\rm{BN}}{{\rm{S}}_{0.245 - 1.5x}}{_{0.5x}}{{\rm{B}}_{0.325 + x}}{\rm{T}}$$ BNS 0.245 − 1.5 x □ 0.5 x B 0.325 + x T ceramics are prepared by using pressureless solid-state sintering and achieve large Wrec (1.8 J/cm3) at a low electric field (@110 kV/cm) when x = 0.06. The value of 1.8 J/cm3 is super high as compared to all other Wrec in lead-free bulk ceramics under a relatively low electric field (< 160 kV/cm). Furthermore, a high dielectric constant of 2930 within 15% fluctuation in a wide temperature range of 40–350 °C is also obtained in $${\rm{BN}}{{\rm{S}}_{0.245 - 1.5x}}{_{0.5x}}{{\rm{B}}_{0.325 + x}}{\rm{T}}$$ BNS 0.245 − 1.5 x □ 0.5 x B 0.325 + x T (x = 0.06) ceramics. The excellent performances can be attributed to the A-site defect engineering, which can reduce remnant polarization (Pr) and improve the thermal evolution of polar nanoregions (PNRs). This work confirms that the $${\rm{BN}}{{\rm{S}}_{0.245 - 1.5x}}{_{0.5x}}{{\rm{B}}_{0.325 + x}}{\rm{T}}$$ BNS 0.245 − 1.5 x □ 0.5 x B 0.325 + x T (x = 0.06) ceramics are desirable for advanced pulsed power capacitors, and will push the development of a series of Bi0.5Na0.5TiO3 (BNT)-based ceramics with high Wrec and high-temperature stability.
- Subjects :
- Materials science
business.industry
Defect engineering
Bi0.5Na0.5TiO3 (BNT)
Clay industries. Ceramics. Glass
Dielectric
Pulsed power
Stability (probability)
Energy storage
Electronic, Optical and Magnetic Materials
relaxor ferroelectrics
energy storage ceramics
ceramic capacitor
defect engineering
TP785-869
visual_art
Ceramics and Composites
visual_art.visual_art_medium
Optoelectronics
Ceramic
business
Subjects
Details
- Language :
- English
- ISSN :
- 22278508 and 22264108
- Volume :
- 11
- Issue :
- 2
- Database :
- OpenAIRE
- Journal :
- Journal of Advanced Ceramics
- Accession number :
- edsair.doi.dedup.....4b49602d51f133e163d251fdd08344e9