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Co-existence of five- and six-coordinate iron(<scp>ii</scp>) species captured in a geometrically strained spin-crossover Hofmann framework

Authors :
Luonan Xu
Zixi Xie
Katrina A. Zenere
Jack K. Clegg
Elise Kenny
Nicole J. Rijs
Guy N. L. Jameson
Cameron J. Kepert
Benjamin J. Powell
Suzanne M. Neville
Source :
Dalton Transactions. 51:9596-9600
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

The use of an angular ligand drives the formation of an irregular Hofmann framework whereby 6-coordinate and rare 5-coordinate FeII species co-exist – the 6-coordinate species show a spin-crossover transition.

Subjects

Subjects :
Inorganic Chemistry

Details

ISSN :
14779234 and 14779226
Volume :
51
Database :
OpenAIRE
Journal :
Dalton Transactions
Accession number :
edsair.doi.dedup.....4ceb0295a3b8a2c908a1a28ef84d2955