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Co-existence of five- and six-coordinate iron(<scp>ii</scp>) species captured in a geometrically strained spin-crossover Hofmann framework
- Source :
- Dalton Transactions. 51:9596-9600
- Publication Year :
- 2022
- Publisher :
- Royal Society of Chemistry (RSC), 2022.
-
Abstract
- The use of an angular ligand drives the formation of an irregular Hofmann framework whereby 6-coordinate and rare 5-coordinate FeII species co-exist – the 6-coordinate species show a spin-crossover transition.
- Subjects :
- Inorganic Chemistry
Subjects
Details
- ISSN :
- 14779234 and 14779226
- Volume :
- 51
- Database :
- OpenAIRE
- Journal :
- Dalton Transactions
- Accession number :
- edsair.doi.dedup.....4ceb0295a3b8a2c908a1a28ef84d2955