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Environmental influence of gaseous emissions from selfheating coal waste dumps in Silesia, Poland
- Source :
- Environmental Geochemistry and Health
- Publication Year :
- 2019
-
Abstract
- Gaseous emissions from seven self-heating coal waste dumps in two large coal mining basins, Upper and Lower Silesia (Poland), were investigated by gas chromatography (GC-FID/TCD), and the results were correlated with on-site thermal activity, stage of self-heating as assessed by thermal mapping, efflorescences, and surface and subsurface temperatures. Though typical gases at sites without thermal activity are dominated by atmospheric nitrogen and oxygen, methane and carbon dioxide are present in concentrations that many times exceed atmospheric values. On average, their concentrations are 42.7–7160 ppm, respectively. These are levels considered harmful to health and show that coal waste fire can be dangerous for some years after extinction. At thermally active sites, concentrations of CH4 and CO2 are much higher and reach 5640–51,976 ppm (aver.), respectively. A good substrate–product correlation between CO2 and CH4 concentrations indicates rapid in-dump CH4 oxidation with only insignificant amounts of CO formed. Other gas components include hydrogen, and C3–C6 saturated and unsaturated hydrocarbons. Decreasing oxygen content in the gases is temperature-dependent, and O2 removal rapidly increased at > 70 °C. Emission differences between both basins are minor and most probably reflect the higher maturity of coal waste organic matter in the Lower Silesia dumps causing its higher resistance to temperature, or/and a higher degree of overburning there. Electronic supplementary material The online version of this article (10.1007/s10653-018-0153-5) contains supplementary material, which is available to authorized users.
- Subjects :
- Environmental Engineering
Chromatography, Gas
010504 meteorology & atmospheric sciences
Nitrogen
chemistry.chemical_element
coal wastes
010501 environmental sciences
01 natural sciences
complex mixtures
Methane
Heating
chemistry.chemical_compound
Geochemistry and Petrology
volatile organic compounds
greenhouse gases
Environmental Chemistry
Organic matter
Coal
0105 earth and related environmental sciences
General Environmental Science
Water Science and Technology
chemistry.chemical_classification
Maturity (geology)
Original Paper
Air Pollutants
gas emission
business.industry
Coal mining
Temperature
self-heating
General Medicine
Carbon Dioxide
Refuse Disposal
Oxygen
Waste Disposal Facilities
chemistry
Environmental chemistry
Greenhouse gas
Carbon dioxide
Environmental science
Gases
Poland
business
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Journal :
- Environmental Geochemistry and Health
- Accession number :
- edsair.doi.dedup.....4d96844f427655783ee6335817b9f775