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Sustainable biopolymer synthesis via superstructure and multiobjective optimization
- Source :
- AIChE Journal. 64:91-103
- Publication Year :
- 2017
- Publisher :
- Wiley, 2017.
-
Abstract
- Sustainable polymers derived from biomass have great potential to replace petrochemical based polymers and fulfill the ever-increasing market demand. To facilitate their industrialization, in this research, a comprehensive superstructure reaction network comprising a large number of reaction pathways from biomass to both commercialized and newly proposed polymers is constructed. To consider economic performance and environmental impact simultaneously, both process profit and green chemistry metrics are embedded into the multiobjective optimization framework, and MINLP is used to enable the effective selection of promising biopolymer candidates. Through this proposed approach, this study identifies the best biopolymer candidates and their most profitable and environmentally friendly synthesis routes under different scenarios. Moreover, the stability of optimization results regarding the price of raw materials and polymers and the effect of process scale on the investment cost are discussed in detail. These results, therefore, pave the way for future research on the production of sustainable biopolymers.
- Subjects :
- MINLP
Technology
Engineering, Chemical
LIMONENE
Environmental Engineering
Materials science
FUELS
General Chemical Engineering
0904 Chemical Engineering
engineering.material
010402 general chemistry
01 natural sciences
Multi-objective optimization
NEXT-GENERATION BIOFUELS
BIO-BASED CHEMICALS
LIGNOCELLULOSIC BIOMASS
Engineering
green chemistry metrics
multiobjective optimization
GAMMA-VALEROLACTONE
BIOHYDROGEN PRODUCTION
SOLVENT
Science & Technology
sustainable biopolymer
010405 organic chemistry
business.industry
PLATFORM
Structural engineering
Chemical Engineering
superstructure optimization
0104 chemical sciences
engineering
Biochemical engineering
Biopolymer
POLYMERS
business
Superstructure (condensed matter)
0914 Resources Engineering And Extractive Metallurgy
Biotechnology
Subjects
Details
- ISSN :
- 00011541
- Volume :
- 64
- Database :
- OpenAIRE
- Journal :
- AIChE Journal
- Accession number :
- edsair.doi.dedup.....4fdfa84230dfe1427b8d3f7e01665a4a
- Full Text :
- https://doi.org/10.1002/aic.15877