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Synthesis of a redox-responsive quadruple hydrogen-bonding unit for applications in supramolecular chemistry
- Source :
- Journal of the American Chemical Society. 133(43)
- Publication Year :
- 2011
-
Abstract
- A redox-responsive quadruple hydrogen-bonding module (eDAN) has been developed. The strong binding between the reduced form and its partner (DeUG) can be significantly decreased upon oxidation but restored upon subsequent reduction. This on–off switch was successfully applied to provide reversible control of macroscopic supramolecular polymer networks.
- Subjects :
- chemistry.chemical_classification
Molecular Structure
Chemistry
Stereochemistry
Hydrogen bond
Macromolecular Substances
Polymers
Supramolecular chemistry
Hydrogen Bonding
General Chemistry
Redox responsive
Biochemistry
Combinatorial chemistry
Catalysis
Supramolecular polymers
Colloid and Surface Chemistry
Thermodynamics
Oxidation-Reduction
Strong binding
Subjects
Details
- ISSN :
- 15205126
- Volume :
- 133
- Issue :
- 43
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....57de4ff859591fda8897625408c5bf34