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Ammonia-assisted fast Li-ion conductivity in a new hemiammine lithium borohydride, LiBH4·1/2NH3
- Source :
- Chemical Communications, Vol. 56, No 28 (2020) pp. 3971-3974, Yan, Y, Grinderslev, J B, Lee, Y S, Jørgensen, M, Cho, Y W, Černý, R & Jensen, T R 2020, ' Ammonia-assisted fast Li-ion conductivity in a new hemiammine lithium borohydride, LiBH 4 ·1/2NH 3 ', Chemical Communications, vol. 56, no. 28, pp. 3971-3974 . https://doi.org/10.1039/c9cc09990e
- Publication Year :
- 2020
-
Abstract
- Hemiammine lithium borohydride, LiBH4·1/2NH3, is characterized and a new Li+ conductivity mechanism is identified. It exhibits a Li+ conductivity of 7 × 10-4 S cm-1 at 40 °C in the solid state and 3.0 × 10-2 S cm-1 at 55 °C after melting. The molten state of LiBH4·1/2NH3 has a high viscosity and can be mechanically stabilized in nano-composites with inert metal oxides and other hydrides making it a promising battery electrolyte.
- Subjects :
- Inert
Materials science
Inorganic chemistry
Metals and Alloys
General Chemistry
ddc:500.2
Conductivity
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ion
Metal
Molten state
Ammonia
chemistry.chemical_compound
Viscosity
chemistry
TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY
Lithium borohydride
visual_art
Materials Chemistry
Ceramics and Composites
visual_art.visual_art_medium
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Database :
- OpenAIRE
- Journal :
- Chemical Communications, Vol. 56, No 28 (2020) pp. 3971-3974, Yan, Y, Grinderslev, J B, Lee, Y S, Jørgensen, M, Cho, Y W, Černý, R & Jensen, T R 2020, ' Ammonia-assisted fast Li-ion conductivity in a new hemiammine lithium borohydride, LiBH 4 ·1/2NH 3 ', Chemical Communications, vol. 56, no. 28, pp. 3971-3974 . https://doi.org/10.1039/c9cc09990e
- Accession number :
- edsair.doi.dedup.....598870aaf3fb873c95cba7219f9c2a50
- Full Text :
- https://doi.org/10.1039/c9cc09990e