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Enantioselective Rauhut-Currier-Type 1,6-Conjugate Addition of Methyl Vinyl Ketone to para-Quinone Methides
- Source :
- Chemistry (Weinheim an der Bergstrasse, Germany). 23(27)
- Publication Year :
- 2017
-
Abstract
- An unprecedented Rauhut-Currier-type 1,6-conjugate addition has been developed. With chiral cyclohexane-based phosphine-amide catalyst 3 h, the 1,6-conjugate reaction has been achieved to produce chiral diarylmethine compounds in excellent yields (91-99 %) and enantioselectivities (92-98 % ee).
Details
- ISSN :
- 15213765
- Volume :
- 23
- Issue :
- 27
- Database :
- OpenAIRE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Accession number :
- edsair.doi.dedup.....5f3b46a08f39804761984c41a98d0eab