Mercuration of acetone in the acetone-mercury(II) perchlorate-2-(2'pyridyl)quinoxaline(L) system

Authors :: Nils Åge Frøystein
Achilleas Garoufis
Nick Hadjiliadis
Spyros P. Perlepes
Jorunn Sletten
Publication Year :: 1996
Publisher :: Elsevier, 1996.
Abstract: The 1:1 reaction of Hg(ClO 4 ) 2 ·3H 2 O with 2-(2′-pyridyl)quinoxaline(L) in acetone leads to isolation of [Hg(CH 2 COCH 3 )(ClO 4 L] 2 ; the X-ray crystal structure determination together with 1 H- and 13 C-NMR spectra reveal the presence of the coordinated 2-oxopropyl anion. L coordinates in a bidentate, highly asymmetric mode.

Subjects :: complexes
Denticity
chemistry.chemical_element
Crystal structure
Photochemistry
Medicinal chemistry
Mercury (element)
Inorganic Chemistry
chemistry.chemical_compound
Perchlorate
Quinoxaline
chemistry
Materials Chemistry
Acetone
2-(2'-pyridyl)quinoxaline
Physical and Theoretical Chemistry

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