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Gold‐Catalyzed Divergent Ring‐Opening Rearrangement of Cyclopropenes Enabled by Dichotomous Gold−Carbenes

Authors :
Tingrui Li
Yilitabaier Julaiti
Xiaopeng Wu
Jie Han
Jin Xie
Source :
Chemistry – A European Journal. 28
Publication Year :
2022
Publisher :
Wiley, 2022.

Abstract

The gold-catalyzed ring-opening rearrangement of cyclopropenes affords an efficient route to either polysubstituted naphthols or aryl-substituted furans. Owing to the unique dichotomy of gold-carbenes, this protocol provides a switchable reaction selectivity between naphthols and furans enabled by the use of TFP-Au(MeCN)SbF

Details

ISSN :
15213765 and 09476539
Volume :
28
Database :
OpenAIRE
Journal :
Chemistry – A European Journal
Accession number :
edsair.doi.dedup.....628270ac05dd5ca7ad3722bab7a7e730
Full Text :
https://doi.org/10.1002/chem.202202851