Enantioselective synthesis of acyclic monohydrosilanes by steric hindrance assisted C–H silylation

Authors :: Delong Mu
Shuqiong Pan
Xiaoyu Wang
Xiaoyun Liao
Yong Huang
Jiean Chen
Source :: Chemical Communications. 58:7388-7391
Publication Year :: 2022
Publisher :: Royal Society of Chemistry (RSC), 2022.
Abstract: Herein, a rhodium-catalyzed desymmetrization of dihydrosilanes with heterocyclic compounds via intermolecular dehydrogenative C–H silylation is developed.

Subjects :: Silicon
Heterocyclic Compounds
Materials Chemistry
Metals and Alloys
Ceramics and Composites
Rhodium
Stereoisomerism
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials

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