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Bulk modulus of a protein active-site mimic
- Source :
- The journal of physical chemistry. B. 115(15)
- Publication Year :
- 2011
-
Abstract
- Flexibility is an important property of porphyrins, both natural and synthetic. We applied two synchrotron-based techniques, nuclear resonance vibrational spectroscopy and inelastic X-ray scattering, to quantify this property by measuring the bulk modulus of a protein active-site mimic [chloro(octaethylporphyrinato)iron(III)] and the resilience of the iron environment. Their values are 6.95 ± 0.24 GPa and 15.4 ± 0.5 N/m, respectively.
- Subjects :
- Hemeproteins
Models, Molecular
Bulk modulus
Materials science
Porphyrins
biology
Scattering
Spectrum Analysis
Analytical chemistry
Active site
A protein
Synchrotron
Surfaces, Coatings and Films
law.invention
law
Biomimetics
Catalytic Domain
Materials Chemistry
biology.protein
Animals
Humans
Resilience (materials science)
Physical and Theoretical Chemistry
Nuclear resonance vibrational spectroscopy
Subjects
Details
- ISSN :
- 15205207
- Volume :
- 115
- Issue :
- 15
- Database :
- OpenAIRE
- Journal :
- The journal of physical chemistry. B
- Accession number :
- edsair.doi.dedup.....6890c738be93afc7d4ba472d66062ef0