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Bulk modulus of a protein active-site mimic

Authors :
W. Robert Scheidt
Ahmet Alatas
Bogdan M. Leu
E. Ercan Alp
Nathan J. Silvernail
Wolfgang Sturhahn
J. Timothy Sage
Source :
The journal of physical chemistry. B. 115(15)
Publication Year :
2011

Abstract

Flexibility is an important property of porphyrins, both natural and synthetic. We applied two synchrotron-based techniques, nuclear resonance vibrational spectroscopy and inelastic X-ray scattering, to quantify this property by measuring the bulk modulus of a protein active-site mimic [chloro(octaethylporphyrinato)iron(III)] and the resilience of the iron environment. Their values are 6.95 ± 0.24 GPa and 15.4 ± 0.5 N/m, respectively.

Details

ISSN :
15205207
Volume :
115
Issue :
15
Database :
OpenAIRE
Journal :
The journal of physical chemistry. B
Accession number :
edsair.doi.dedup.....6890c738be93afc7d4ba472d66062ef0