Back to Search
Start Over
Synthesis of Some Mono-, Bis- NH-substituted-1,4-Benzoquinones
- Source :
- Volume: 5, Issue: 2 963-970, Journal of the Turkish Chemical Society Section A: Chemistry, Journal of the Turkish Chemical Society, Section A: Chemistry, Vol 5, Iss 2, Pp 963-970 (2018)
- Publication Year :
- 2018
- Publisher :
- The Turkish Chemical Society, 2018.
-
Abstract
- The preparation of new mono- and bis- NH-substituted-1,4-benzoquinones, namely 2,5-bis(5,6-dimethylbenzo[d]thiazol-2-ylamino)cyclohexa-2,5-diene-1,4-dione ( 3 ), 2,5-bis(3-(2-methylpiperidin-1-yl)propylamino)-3-chlorocyclohexa-2,5-diene-1,4-dione ( 6 ), 2-(4-tert-butylbenzylamino)-3,5,6-trichlorocyclohexa-2,5-diene-1,4-dione ( 9 ), 2-(4-fluorophenylamino)-6-tert-butylcyclohexa-2,5-diene-1,4-dione ( 12 ) is reported. The synthesis of new quinone derivatives ( 3 , 6 , 9 , 12 ) have been carried out from the reactions between quinones ( p -benzoquinone ( 1 ), 2,6-dichloro-1,4-benzoquinone ( 4 ), tetrachloro-1,4-benzoquinone ( 7 ), 2-tert-butyl-1,4-benzoquinone ( 10 )) and different amines (2-Amino-5,6-dimethylbenzothiazole ( 2 ), N-(3-aminopropyl)-2-pipecoline ( 5 ), 4-tert-butylbenzylamine ( 8 ), 4-fluoroaniline ( 11 )). The new compounds were characterized by elemental analysis, mass spectrometry, IR, 1 H-NMR, 13 C-NMR spectroscopy.
- Subjects :
- 010405 organic chemistry
Chemistry
Quinones,NH-substituted-benzoquinones,Amines
Quinones
General Chemistry
010402 general chemistry
Mass spectrometry
Elektrokimya
01 natural sciences
Medicinal chemistry
Benzoquinone
0104 chemical sciences
Quinone
lcsh:Chemistry
NH-substituted-benzoquinones
lcsh:QD1-999
Elemental analysis
Electrochemistry
Amines
Spectroscopy
Subjects
Details
- ISSN :
- 21490120
- Volume :
- 5
- Database :
- OpenAIRE
- Journal :
- Journal of the Turkish Chemical Society Section A: Chemistry
- Accession number :
- edsair.doi.dedup.....69e7478a4ab1912601238e08d8afc8ea