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Total Synthesis of Aeruginosin 98B
- Source :
- Journal of the American Chemical Society. 134:18944-18947
- Publication Year :
- 2012
- Publisher :
- American Chemical Society (ACS), 2012.
-
Abstract
- The first total synthesis of aeruginosin 98B (1) was accomplished. The key step includes a highly diastereoselective Pd-catalyzed intramolecular asymmetric allylic alkylation (AAA) reaction of a diastereomeric mixture of allylic carbonates, which is enabled by the use of racemic phosphine ligand L1.
Details
- ISSN :
- 15205126 and 00027863
- Volume :
- 134
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....6cbfe933952486b563a7e316b8ee906a