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Design of Fe-containing GdTbCoAl high-entropy-metallic-glass composite microwires with tunable Curie temperatures and enhanced cooling efficiency
- Source :
- Digital.CSIC: Repositorio Institucional del CSIC, Consejo Superior de Investigaciones Científicas (CSIC), Materials & Design, Vol 206, Iss, Pp 109824-(2021), Digital.CSIC. Repositorio Institucional del CSIC, instname
- Publication Year :
- 2021
- Publisher :
- Elsevier, 2021.
-
Abstract
- Through designing the composition and processing approach, the non-equiatomic (Gd36Tb20Co20Al24)100- xFex (x = 0, 1, 2 and 3 at.%) high-entropy-metallic-glass (HE-MG) alloy microwires were successfully fabricated by melt-extraction technique. The microstructure and magnetocaloric properties of the microwires were systematically investigated. The microwires possess tunable Curie temperatures, i.e. 81– 108 K, above the typical rare-earth (RE) containing HE-MG reports. The high Curie temperatures are attributed to the designed composition. Magnetocaloric response peak values of Fe-containing GdTbCoAl alloy microwires range 7.6–8.9 J kg1 K1 (5 T), which are comparable to those of many outstanding RE-containing magnetocaloric HE-MGs. The characteristics of the melt-extraction method, combining with compositional effects, favor the formation of amorphous and nanocrystalline phases. The increase in the cooling efficiency for microwires with higher Fe content can be attributed to the broadening of the Curie temperature distribution induced by the composition difference between nanocrystalline phase and amorphous matrix. The designed composition and the melt-extraction processing approach for Fe-containing GdTbCoAl alloys can tune their Curie temperatures towards a temperature range of natural gas liquefaction and improve their magnetocaloric properties. This demonstrates that Fe-containing GdTbCoAl HE-MG composite microwires have great potential as high-performance magnetic refrigerants
- Subjects :
- Materials science
Magnetocaloric effect
02 engineering and technology
010402 general chemistry
01 natural sciences
Microwires
Curie
Magnetic refrigeration
General Materials Science
Composite material
Materials of engineering and construction. Mechanics of materials
Amorphous metal
Mechanical Engineering
Cooling efficiency
Atmospheric temperature range
021001 nanoscience & nanotechnology
Microstructure
Fe-doping
Nanocrystalline material
0104 chemical sciences
Amorphous solid
Mechanics of Materials
TA401-492
Curie temperature
Dual-phase microstructure
0210 nano-technology
Subjects
Details
- Database :
- OpenAIRE
- Journal :
- Digital.CSIC: Repositorio Institucional del CSIC, Consejo Superior de Investigaciones Científicas (CSIC), Materials & Design, Vol 206, Iss, Pp 109824-(2021), Digital.CSIC. Repositorio Institucional del CSIC, instname
- Accession number :
- edsair.doi.dedup.....6cdef5109eac32a779e3cdc825502460
- Full Text :
- https://doi.org/10.1016/j.matdes.2021.109824