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trans-Dichloridobis(2,2-dimethylpropane-1,3-diamine-κ2N,N′)chromium(III) perchlorate
- Source :
- Acta Crystallographica Section E: Structure Reports
- Publication Year :
- 2008
- Publisher :
- International Union of Crystallography (IUCr), 2008.
-
Abstract
- In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octa-hedral environment comprising the four N atoms of two chelating 2,2-dimethyl-propane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair-chair conformations with respect to each other. The perchlorate anion is disordered over two positions in respect of the Cl and an O atom in a 6:4 ratio. N-H⋯O hydrogen bonds link the cations and anions into a layer structure.
- Subjects :
- Metal-Organic Papers
chemistry.chemical_classification
Hydrogen bond
Salt (chemistry)
chemistry.chemical_element
General Chemistry
Condensed Matter Physics
Bioinformatics
Medicinal chemistry
Ion
Perchlorate
chemistry.chemical_compound
Chromium
chemistry
Diamine
Atom
General Materials Science
Chelation
Subjects
Details
- ISSN :
- 16005368
- Volume :
- 64
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E Structure Reports Online
- Accession number :
- edsair.doi.dedup.....6de525796b9b012f06d02cece56aeffa