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Describing screening in dense ionic fluids with a charge-frustrated Ising model
- Publication Year :
- 2018
-
Abstract
- Charge correlations in dense ionic fluids give rise to novel effects such as long-range screening and colloidal stabilization which are not predicted by the classic Debye-Huckel theory. We show that a Coulomb or charge-frustrated Ising model, which accounts for both long-range Coulomb and short-range molecular interactions, simply describes some of these ionic correlations. In particular, we obtain at mean field level and in simulations, a non-monotonic dependence of the screening length on the temperature. Using a combination of simulations and mean field theories, we study how the correlations in the various regimes are affected by the strength of the short ranged interactions.<br />8 pages, 6 figures
- Subjects :
- Physics
Molecular interactions
Condensed matter physics
Statistical Mechanics (cond-mat.stat-mech)
General Physics and Astronomy
Ionic bonding
FOS: Physical sciences
Charge (physics)
02 engineering and technology
Condensed Matter - Soft Condensed Matter
021001 nanoscience & nanotechnology
01 natural sciences
Colloid
Mean field theory
0103 physical sciences
Coulomb
Soft Condensed Matter (cond-mat.soft)
Ising model
Physical and Theoretical Chemistry
010306 general physics
0210 nano-technology
Condensed Matter - Statistical Mechanics
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....70daebab15667dc25bfd138d3f71cc4a