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Describing screening in dense ionic fluids with a charge-frustrated Ising model

Authors :
Kinjal Dasbiswas
Nicholas B. Ludwig
Dmitri V. Talapin
Suriyanarayanan Vaikuntanathan
Publication Year :
2018

Abstract

Charge correlations in dense ionic fluids give rise to novel effects such as long-range screening and colloidal stabilization which are not predicted by the classic Debye-Huckel theory. We show that a Coulomb or charge-frustrated Ising model, which accounts for both long-range Coulomb and short-range molecular interactions, simply describes some of these ionic correlations. In particular, we obtain at mean field level and in simulations, a non-monotonic dependence of the screening length on the temperature. Using a combination of simulations and mean field theories, we study how the correlations in the various regimes are affected by the strength of the short ranged interactions.<br />8 pages, 6 figures

Details

Language :
English
Database :
OpenAIRE
Accession number :
edsair.doi.dedup.....70daebab15667dc25bfd138d3f71cc4a