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(E)-4-Meth­oxy-N′-(2,4,5-tri­meth­oxy­benzyl­idene)benzohydrazide hemihydrate

Authors :
Nawong Boonnak
Ching Kheng Quah
Hoong-Kun Fun
Jirapa Horkaew
Suchada Chantrapromma
Source :
Acta Crystallographica Section E: Structure Reports, Acta Crystallographica Section E, Vol 70, Iss 2, Pp o150-o151 (2014)
Publication Year :
2014
Publisher :
International Union of Crystallography, 2014.

Abstract

The title compound crystallizes as a hemihydrate, C18H20N2O5·0.5H2O. The molecule exists in anEconformation with respect to the C=N imine bond. The 4-methoxyphenyl unit is disordered over two sets of sites with a refined occupancy ratio of 0.54 (2):0.46 (2). The dihedral angles between the benzene rings are 29.20 (9) and 26.59 (9)°, respectively, for the major and minor components of the 4-methoxy-substituted ring. All methoxy substituents lie close to the plane of the attached benzene rings [the Cmethyl—O—C—C torsion angles range from −4.0 (12) to 3.9 (2)°]. In the crystal, the components are linked into chains propagating along [001]viaN—H...O and O—H...O hydrogen bonds and weak C—H...O interactions.

Details

Language :
English
ISSN :
16005368
Volume :
70
Issue :
Pt 2
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E: Structure Reports Online
Accession number :
edsair.doi.dedup.....717aa9db043c1b4d74771d424b1de22f