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Efficient Construction of Oxa- and Aza-[n.2.1] Skeletons: Lewis Acid Catalyzed Intramolecular [3+2] Cycloaddition of Cyclopropane 1,1-Diesters with Carbonyls and Imines
- Source :
- Angewandte Chemie. 122:3283-3286
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- A Lewis acid promoted intramolecular [3+2] cycloaddition of cyclopropane 1,1-diesters with aldehydes, ketones, and imines is developed to provide a general and efficient strategy for construction of bridged oxa- and aza-[n.2.1] skeletons.
- Subjects :
- Cyclopropanes
Models, Molecular
Aldehydes
Aza Compounds
Molecular Structure
Stereochemistry
Stereoisomerism
Esters
General Chemistry
General Medicine
Ketones
Crystallography, X-Ray
Cycloaddition
Catalysis
Cyclopropane
chemistry.chemical_compound
chemistry
Cyclization
Intramolecular force
Molecule
Lewis acids and bases
Imines
Acids
Subjects
Details
- ISSN :
- 15213757 and 00448249
- Volume :
- 122
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie
- Accession number :
- edsair.doi.dedup.....724a0662b260d1cb8d68b94a014d5004