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1-Methanesulfonyl-1a,2,6,6a-tetrahydro-1H,4H-[1,3]dioxepino[5,6-b]azirine
- Source :
- Acta Crystallographica Section C Crystal Structure Communications. 49:1661-1663
- Publication Year :
- 1993
- Publisher :
- International Union of Crystallography (IUCr), 1993.
-
Abstract
- The dioxepine part of the title heterocycle adopts a chair conformation. The position of O1 opposite to the lone pair at the N atom and the inequality of the bond angles O1-S1-N1>>O2-S1-N1 suggest an n-s* interaction of the lone-electron pair with the SVI[O, O', N, C]tetrahedral moiety.
- Subjects :
- chemistry.chemical_classification
Azirine
Bicyclic molecule
Stereochemistry
Cyclohexane conformation
General Medicine
Crystal structure
General Biochemistry, Genetics and Molecular Biology
Sulfonamide
chemistry.chemical_compound
Molecular geometry
chemistry
Moiety
Lone pair
[1
3]-dioxepino[5
6-b]azirine
1
3-dioxepine
X-ray
single crystal
Subjects
Details
- ISSN :
- 01082701
- Volume :
- 49
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section C Crystal Structure Communications
- Accession number :
- edsair.doi.dedup.....72f1610ad733d6f59f7132d098ef7cbe