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Macroscopic Polarization Change of Mononuclear Valence Tautomeric Cobalt Complexes Through the Use of Enantiopure Ligand
- Source :
- Chemistry – A European Journal. 28
- Publication Year :
- 2022
- Publisher :
- Wiley, 2022.
-
Abstract
- The crystallization of a complex having electron transfer properties in a polar space group can induce the polarization switching of a crystal in a specific direction, which is attractive for the development of sensors, memory devices, and capacitors. Unfortunately, the probability of crystallization in a polar space group is usually low. Noticing that enantiopure compounds crystallize in Sohncke space groups, this paper reports a strategy for the molecular design of non-ferroelectric polarization switching crystals based on the use of intramolecular electron transfer and chirality. In addition, this paper describes the synthesis of a mononuclear valence tautomeric (VT) cobalt complex bearing an enantiopure ligand. The introduction of enantiomer enables the crystallization of the complex in the polar space group (P2
- Subjects :
- Organic Chemistry
General Chemistry
Catalysis
Subjects
Details
- ISSN :
- 15213765 and 09476539
- Volume :
- 28
- Database :
- OpenAIRE
- Journal :
- Chemistry – A European Journal
- Accession number :
- edsair.doi.dedup.....73cc68db5c8d9e3c3b517804657803fa
- Full Text :
- https://doi.org/10.1002/chem.202202161