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Difluoromethylcarbene for iron-catalyzed cyclopropanation
- Source :
- Chemical communications (Cambridge, England). 53(27)
- Publication Year :
- 2017
-
Abstract
- Difluoroethylsulfonium salt, Ph2S+CH2CF2H OTf−, was developed into a convenient difluoromethylcarbene reagent for the iron-catalyzed cyclopropanation of terminal olefins, giving various difluoromethyl–cyclopropanes with excellent diastereoselectivities and in high yields.
- Subjects :
- chemistry.chemical_classification
010405 organic chemistry
Cyclopropanation
Iron catalyzed
Metals and Alloys
Salt (chemistry)
General Chemistry
010402 general chemistry
01 natural sciences
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry
Reagent
Materials Chemistry
Ceramics and Composites
Organic chemistry
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 53
- Issue :
- 27
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....7577538790673ec3a7182a738180065e