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A-Site Order Control in Mixed Conductor NdBaCo 2 O 5+δ Films through Manipulation of Growth Kinetics

Authors :
Hongjun Niu
Lei Yan
Paul R. Chalker
D. Giap
Zhongling Xu
S. R. C. McMitchell
Matthew J. Rosseinsky
John Bacsa
C. Grygiel
University of Liverpool
Source :
Chemistry of Materials, Chemistry of Materials, American Chemical Society, 2010, 22 (6), pp.1955-1957. ⟨10.1021/cm9037022⟩, BASE-Bielefeld Academic Search Engine
Publication Year :
2010
Publisher :
HAL CCSD, 2010.

Abstract

NdBaCo2O5+δ films have been grown on (001)-SrTiO3 substrates using pulsed laser deposition with RHEED to access both A-site ordered and A-site disordered films grown in a layer-by-layer manner. Ionic diffusion kinetics are shown to be key parameter for A-site order, attained by control of growth kinetics, mobility, and supersaturation.

Details

Language :
English
ISSN :
08974756 and 15205002
Database :
OpenAIRE
Journal :
Chemistry of Materials, Chemistry of Materials, American Chemical Society, 2010, 22 (6), pp.1955-1957. ⟨10.1021/cm9037022⟩, BASE-Bielefeld Academic Search Engine
Accession number :
edsair.doi.dedup.....763e983fe4c0f42f57af046da649e1a8
Full Text :
https://doi.org/10.1021/cm9037022⟩