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Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window
- Source :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2021, 57 (31), pp.3793-3796. ⟨10.1039/d1cc00898f⟩, Chemical Communications, 2021, 57 (31), pp.3793-3796. ⟨10.1039/d1cc00898f⟩, Chemical Communications, Vol. 57, No 31 (2021) pp. 3793-3796
- Publication Year :
- 2021
- Publisher :
- HAL CCSD, 2021.
-
Abstract
- International audience; Synthesis, electronic and structural properties of a chiral NHC bearing a N-bonded cationic [4]helicene moiety are reported. This ligand is used to construct Au(I), Au(III) and Rh(I) complexes exhibiting far-red (chir)optical properties regardless of the metal.
- Subjects :
- 010402 general chemistry
01 natural sciences
Catalysis
Metal
chemistry.chemical_compound
Materials Chemistry
Moiety
[CHIM]Chemical Sciences
010405 organic chemistry
Ligand
Spectral window
Metals and Alloys
Cationic polymerization
Far-red
General Chemistry
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Crystallography
Helicene
chemistry
visual_art
ddc:540
Ceramics and Composites
visual_art.visual_art_medium
Carbene
Subjects
Details
- Language :
- English
- ISSN :
- 13597345 and 1364548X
- Database :
- OpenAIRE
- Journal :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2021, 57 (31), pp.3793-3796. ⟨10.1039/d1cc00898f⟩, Chemical Communications, 2021, 57 (31), pp.3793-3796. ⟨10.1039/d1cc00898f⟩, Chemical Communications, Vol. 57, No 31 (2021) pp. 3793-3796
- Accession number :
- edsair.doi.dedup.....7648c6ecd847df527c13529e47615f98