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The effect of water in the low-temperature catalytic oxidation of hydrogen sulfide to sulfur over activated carbon

Authors :
Paolo Andreussi
Giuliano Dolcetti
Alessandro Trovarelli
Alessandra Primavera
Source :
Scopus-Elsevier
Publication Year :
1998

Abstract

This study investigates the use of low-temperature catalytic oxidation for the removal of H 2 S from tail gases originating from geothermal plants, with special focus on the effect of water on the overall performance of the activated carbon catalyst. It is shown that water strongly influences the reaction rate and the total amount of sulfur that can be adsorbed on the catalyst prior to regeneration. It is suggested that the reaction takes place in a thin water layer, inside the carbon pores, from the reaction of dissolved H 2 S with chemisorbed oxygen.

Details

Language :
English
Database :
OpenAIRE
Journal :
Scopus-Elsevier
Accession number :
edsair.doi.dedup.....76f8503fa71518da0f3ed16da6a7ac5d