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Conversion of Organic Matter in Coal by Photocatalytic Oxidation with H2O2 over SFC/TiO2 in Isolated Oxygen System
- Source :
- Journal of Chemistry, Vol 2019 (2019)
- Publication Year :
- 2019
- Publisher :
- Hindawi, 2019.
-
Abstract
- Shenfu bituminous coal (SFBC), Geting coal (GTC), Shengli lignite (SLL), and Holingola coal (HLGLC) were oxidized by UV light radiation with aqueous H2O2 over SFC/TiO2 in a closed suspension system (CSS) to understand structural characteristics of 4 typical Chinese coals. Raw and oxidized coals were dried and extracted with acetone thoroughly to ensure residue extraction. Meanwhile, the extracts were analyzed using a gas chromatograph/mass spectrometer. The results show that organic matters (OMs) in coals can be converted into a large number of oxygen-containing organic compounds (OCOCs), mainly containing ketones, esters, alcohols, etc. Oxidizing species such as hydroxyls, hydroperoxyl, and alkyl radicals are excited by light irradiation and substitute for hydrogen atoms of methyls and methylenes of acenes or branched-chain alkanes in coals. Acetic acid and acetaldehyde can be formed and dissolved in aqueous solution in the oxidation reaction. The yields can be improved with the enhancement of the oxidation effect.
- Subjects :
- Article Subject
020209 energy
Inorganic chemistry
geology
02 engineering and technology
complex mixtures
lcsh:Chemistry
chemistry.chemical_compound
020401 chemical engineering
Oxidizing agent
0202 electrical engineering, electronic engineering, information engineering
Acetone
otorhinolaryngologic diseases
Coal
Organic matter
0204 chemical engineering
chemistry.chemical_classification
Bituminous coal
Aqueous solution
business.industry
geology.rock_type
General Chemistry
chemistry
Hydroperoxyl
lcsh:QD1-999
Photocatalysis
business
Subjects
Details
- Language :
- English
- ISSN :
- 20909063
- Database :
- OpenAIRE
- Journal :
- Journal of Chemistry
- Accession number :
- edsair.doi.dedup.....77010a3f5f089631a1895f88eac570bd
- Full Text :
- https://doi.org/10.1155/2019/1768351