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An Error in Determination of Photoinduced Electron Transfer Rates in Langmuir-Blodgett Films
- Source :
- Scopus-Elsevier
- Publication Year :
- 1998
- Publisher :
- The Chemical Society of Japan, 1998.
-
Abstract
- In Langmuir-Blodgett (LB) films consisting of viologen (V2+)-pyrene (Py) dyads, the accumulation of viologen cation radical (V+·) was observed during UV irradiation under N2. The additional quenching due to energy transfer by the colored V+· resulted in an error in determination of photoinduced electron transfer rates between the V2+ and Py moieties in the LB films. This type of error can be generally expected in LB films and self-assembled monolayers.
Details
- ISSN :
- 13480715 and 03667022
- Volume :
- 27
- Database :
- OpenAIRE
- Journal :
- Chemistry Letters
- Accession number :
- edsair.doi.dedup.....7703cb8ddc4952751433988369f4c331
- Full Text :
- https://doi.org/10.1246/cl.1998.701