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Limits of Vinylidene Fluoride RAFT Polymerization
- Source :
- Macromolecules, Macromolecules, 2016, 49, pp.5386−5396. ⟨10.1021/acs.macromol.6b01087⟩, Macromolecules, American Chemical Society, 2016, 49, pp.5386−5396. ⟨10.1021/acs.macromol.6b01087⟩
- Publication Year :
- 2016
- Publisher :
- American Chemical Society (ACS), 2016.
-
Abstract
- International audience; The investigations reported in this article probe the behavior of the RAFT polymerization of vinylidene fluoride (VDF) when degrees of polymerization higher than 50 are targeted: they demonstrate that higher molar mass PVDF (11 000 g mol–1) can indeed be prepared by RAFT polymerization, but only at rather low monomer conversions (
- Subjects :
- Kinetic chain length
Polymers and Plastics
Bulk polymerization
Reversible deactivation radical polymerization
DFT calculations
010402 general chemistry
01 natural sciences
Vinylidene fluoride
Inorganic Chemistry
Chain-growth polymerization
Radical polymerization
Polymer chemistry
Activation energy
Materials Chemistry
Reversible addition−fragmentation chain-transfer polymerization
Reversed addition
Xanthate
010405 organic chemistry
Chemistry
Organic Chemistry
Chain transfer
NMR
0104 chemical sciences
[CHIM.POLY]Chemical Sciences/Polymers
Polymerization
Living polymerization
Mechanism
Ionic polymerization
RAFT
Subjects
Details
- ISSN :
- 15205835 and 00249297
- Volume :
- 49
- Database :
- OpenAIRE
- Journal :
- Macromolecules
- Accession number :
- edsair.doi.dedup.....7acb454c68015ce74bc0ef59bf095415
- Full Text :
- https://doi.org/10.1021/acs.macromol.6b01087