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Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO2 to CO reduction in water
- Source :
- Chemical Communications, Chemical Communications, 2018, 54 (82), pp.11630-11633. ⟨10.1039/c8cc06475j⟩, Chemical Communications, Royal Society of Chemistry, 2018, 54 (82), pp.11630-11633. ⟨10.1039/c8cc06475j⟩
- Publication Year :
- 2018
- Publisher :
- HAL CCSD, 2018.
-
Abstract
- International audience; In this study we report a strategy to attach methylimidazolium fragments as ionic liquid units on an established iron porphyrin catalyst for the selective reduction of CO2 to CO. Importantly, we found that the tetra-methylimidazolium containing porphyrin exhibits an exalted electrocatalytic activity at low overpotential in water precluding the need for an external proton donor.
- Subjects :
- Proton
010405 organic chemistry
Inorganic chemistry
Metals and Alloys
General Chemistry
Overpotential
010402 general chemistry
01 natural sciences
Porphyrin
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Reduction (complexity)
chemistry.chemical_compound
chemistry
Ionic liquid
Materials Chemistry
Ceramics and Composites
polycyclic compounds
[CHIM]Chemical Sciences
Selective reduction
heterocyclic compounds
Subjects
Details
- Language :
- English
- ISSN :
- 13597345 and 1364548X
- Database :
- OpenAIRE
- Journal :
- Chemical Communications, Chemical Communications, 2018, 54 (82), pp.11630-11633. ⟨10.1039/c8cc06475j⟩, Chemical Communications, Royal Society of Chemistry, 2018, 54 (82), pp.11630-11633. ⟨10.1039/c8cc06475j⟩
- Accession number :
- edsair.doi.dedup.....7c462fbd7adee0d8057e7625b7a1d9d3
- Full Text :
- https://doi.org/10.1039/c8cc06475j⟩