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Lanthanum (III) encapsulated chitosan-montmorillonite composite for the adsorptive removal of phosphate ions from aqueous solution
- Source :
- International journal of biological macromolecules. 112
- Publication Year :
- 2017
-
Abstract
- In the present work, lanthanum (III) encapsulated chitosan-montmorillonite composite (La-CS-MMT) was prepared as an adsorbent for the effective removal of phosphate ions from aqueous solution. Characterization of the adsorbent using FT-IR, XRD, SEM with EDX, TGA and DTA techniques were carried out. Batch adsorption experiments were carried out to optimize the effects of various operating parameters viz., shaking time, initial concentration of phosphate ions, dosage, competitor co-existing ions, pH and temperature. Phosphate ions adsorbed effectively on La-CS-MMT composite through hydrogen bonding and by outer-sphere complex formation mechanism. Freundlich isotherm model fit well with the equilibrium isotherm data. The experimental values of ∆G°, ∆S° and ∆H° revealed that the nature of adsorption was feasible, spontaneous and exothermic. The kinetic study was well fitted with pseudo-second-order model. Regeneration study of the spent La-CS-MMT-P composite was carried out upto five cycles and found that about 70% of adsorption efficiency was retained.
- Subjects :
- Composite number
chemistry.chemical_element
02 engineering and technology
010402 general chemistry
01 natural sciences
Biochemistry
Phosphates
Water Purification
Chitosan
chemistry.chemical_compound
Adsorption
Structural Biology
Lanthanum
Humans
Freundlich equation
Molecular Biology
Ions
Aqueous solution
Water
General Medicine
021001 nanoscience & nanotechnology
Phosphate
0104 chemical sciences
Kinetics
Montmorillonite
chemistry
Bentonite
0210 nano-technology
Water Pollutants, Chemical
Nuclear chemistry
Subjects
Details
- ISSN :
- 18790003
- Volume :
- 112
- Database :
- OpenAIRE
- Journal :
- International journal of biological macromolecules
- Accession number :
- edsair.doi.dedup.....7e1de235ca3f8fdbb094b08106b448af