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An exactly solvable model for a ternary solution with three-body interactions and orientationally dependent bonding

Authors :
Florin D. Buzatu
Radu P. Lungu
Dale A. Huckaby
Source :
The Journal of Chemical Physics. 121:6195-6206
Publication Year :
2004
Publisher :
AIP Publishing, 2004.

Abstract

A model is considered in which the bonds of a honeycomb lattice are covered by rodlike molecules of types AA, BB, and AB. Neighboring molecular ends have three-body and orientation-dependent interactions. The model is shown to be equivalent to a spin-1/2 Ising model on the same lattice with a field, but with only pairwise interactions. Symmetric and asymmetric coexistence surfaces for the separation into an AA-rich and a BB-rich phase are calculated exactly.

Details

ISSN :
10897690 and 00219606
Volume :
121
Database :
OpenAIRE
Journal :
The Journal of Chemical Physics
Accession number :
edsair.doi.dedup.....7e8152ae90ec16b5648f1077a08b492e
Full Text :
https://doi.org/10.1063/1.1788633