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A new Ni(dmit)2-based organic magnetic charge-transfer salt, (m-PO-CONH-N-methylpyridinium)[Ni(dmit)2]·CH3CN
- Source :
- Inorganica Chimica Acta. 482:654-658
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- A new Ni(dmit)2-based organic magnetic charge-transfer (CT) salt, (m-PO-CONH-N-methylpyridinium)[Ni(dmit)2]·CH3CN, where PO = 2,2,5,5-Tetramethyl-3-pyrrolin-1-oxyl free radical and dmit = 2-Thioxo-1,3-dithiole-4,5-dithiolate, was obtained, the crystal structure and magnetic properties of which are reported. Magnetic susceptibility of the CT salt obeys a combination of 1D ferromagnetic (1DF) Heisenberg (J1DF = +0.26 K) and Singlet-Triplet (ST) models (JST = -51.2 K) with mean field (MF) approximation (JMF = -6.7 K), suggesting that spins on the PO radicals form 1D ferromagnetic chains and spins on the Ni(dmit)2 monoanions forms spin dimers at low temperature, the latter of which was also confirmed by band calculations.
- Subjects :
- chemistry.chemical_classification
Spins
010405 organic chemistry
Radical
Salt (chemistry)
Crystal structure
010402 general chemistry
01 natural sciences
Magnetic susceptibility
0104 chemical sciences
Inorganic Chemistry
Crystallography
chemistry
Ferromagnetism
Mean field theory
Materials Chemistry
Physical and Theoretical Chemistry
Spin (physics)
Subjects
Details
- ISSN :
- 00201693
- Volume :
- 482
- Database :
- OpenAIRE
- Journal :
- Inorganica Chimica Acta
- Accession number :
- edsair.doi.dedup.....85ebb8d6c101371d387461db002832c4
- Full Text :
- https://doi.org/10.1016/j.ica.2018.07.003