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A Mild Radical Procedure for the Reduction of B-Alkylcatecholboranes to Alkanes
- Source :
- Journal of the American Chemical Society. 127:14204-14205
- Publication Year :
- 2005
- Publisher :
- American Chemical Society (ACS), 2005.
-
Abstract
- A mild radical-mediated reduction of organoboranes is reported. The reducing agent is methanol complexed by the Lewis acidic B-methoxycatecholborane.
- Subjects :
- Sulfonyl
chemistry.chemical_classification
Reaction mechanism
Molecular Structure
Bicyclic molecule
Chemistry
Radical procedure
Reducing agent
Stereoisomerism
General Medicine
General Chemistry
Medicinal chemistry
Biochemistry
Catalysis
Reduction (complexity)
chemistry.chemical_compound
Colloid and Surface Chemistry
Alkanes
Alkoxy group
Organic chemistry
Methanol
Boranes
Oxidation-Reduction
Subjects
Details
- ISSN :
- 15205126 and 00027863
- Volume :
- 127
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....8602b5448bf9ebb291a37f672c4bd730
- Full Text :
- https://doi.org/10.1021/ja055691j