Unexpected, photochemically induced activation of the tetrabutylammonium cation by hexachloroplatinate(iv)

Authors :: Navpreet K. Sethi
Adrian C. Whitwood
Victor Chechik
Imelda H. Silalahi
Duncan W. Bruce
Marsel Z. Shafikov
Source :: Chem. Commun., Chemical Communications
Publication Year :: 2018
Publisher :: Royal Society of Chemistry, 2018.
Abstract: A dinuclear, butadiene-bridged complex, trans-μ2:η2,η2-1,3-butadiene-bis(trichloroplatinate(ii)) (1) was unexpectedly obtained on photolysis of acetone solutions of (NBu4)2[PtCl6].

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