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Stereochemistry of Protiodesilylation of 3-Trimethylsilyl-2-Thiabicyclo[2.2.1]Heptenes, Heptanes and Derivatives
- Source :
- Phosphorus, Sulfur, and Silicon and the Related Elements. 95:379-380
- Publication Year :
- 1994
- Publisher :
- Informa UK Limited, 1994.
-
Abstract
- Some 3-trimethylsilyl-2-thiabicyclo[2.2.1]heptenes and heptanes of known configuration were protiodesilylated and the stereochemistry of the reaction was studied. Evidences for a carbanionic intermediate as well as the pivotal role played by the metal counter-ion are described.
Details
- ISSN :
- 15635325 and 10426507
- Volume :
- 95
- Database :
- OpenAIRE
- Journal :
- Phosphorus, Sulfur, and Silicon and the Related Elements
- Accession number :
- edsair.doi.dedup.....8794e4018f07759ac6715522c53f766c
- Full Text :
- https://doi.org/10.1080/10426509408034242