Ball milling and acetic acid co-modified sludge biochar enhanced by electrochemistry to activate peroxymonosulfate for sustainable degradation of environmental concentration neonicotinoids

Neonicotinoids pose potential serious risks to human health even at environmental concentration and their removal from water is considered as a great challenge. A novel ball milling and acetic acid co-modified sludge biochar (BASBC) was the first time synthesized, which performed superior physicochemical characteristics including larger surface area, more defect structures and functional groups (e.g., CO and -OH). Electrochemistry was introduced to enhance BASBC for peroxymonosulfate (PMS) activation (E/BASBC/PMS) to degrade environmental concentration neonicotinoids (e.g., imidacloprid (IMI)). The degradation efficiency of IMI was 95.2% within 60 min (C