Back to Search
Start Over
Selective Catalytic Oxidation of Diglycerol
- Source :
- Green Chemistry, Green Chemistry, Royal Society of Chemistry, 2021, 23 (3), pp.1154-1159. ⟨10.1039/D0GC03239E⟩
- Publication Year :
- 2021
- Publisher :
- HAL CCSD, 2021.
-
Abstract
- International audience; The selective oxidation of alpha-alpha-diglycerol was studied using oxygen as a clean oxidant in the presence of a palladium / neocuproine complex. After optimization of the reaction parameters, the mono-oxidation product was obtained with 93% NMR yield (up to 76% isolated yield). The product was named "diglycerose" considering that it mainly exists as a cyclic hemi-ketal form.
- Subjects :
- 010405 organic chemistry
Inorganic chemistry
chemistry.chemical_element
010402 general chemistry
01 natural sciences
Pollution
Oxygen
0104 chemical sciences
Neocuproine
chemistry.chemical_compound
chemistry
Product (mathematics)
Yield (chemistry)
Selective catalytic oxidation
Environmental Chemistry
[CHIM]Chemical Sciences
Palladium
Subjects
Details
- Language :
- English
- ISSN :
- 14639262 and 14639270
- Database :
- OpenAIRE
- Journal :
- Green Chemistry, Green Chemistry, Royal Society of Chemistry, 2021, 23 (3), pp.1154-1159. ⟨10.1039/D0GC03239E⟩
- Accession number :
- edsair.doi.dedup.....8d816284fd138a2c2295acf4fd69e774
- Full Text :
- https://doi.org/10.1039/D0GC03239E⟩