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Mechanism of the Hydroxycarbonylation of 1-Hexene Catalyzed by Immobilized Rhodium Complexes of Pyridine Ligands

Authors :
Alvaro J. Pardey
Gabriela C. Uzcátegui
Marisol C. Ortega
Clementina Longo
Fernando Hung-Low
Source :
ChemInform. 38
Publication Year :
2007
Publisher :
Wiley, 2007.

Abstract

In this work, a mechanistic study of the hydroxycarbonylation of 1-hexene to heptanoic acid and the water gas shift reaction (WGSR) catalyzed by the rhodium(I) complexes, [Rh(COD)(amine)2](PF6) (COD = 1,5-cyclooctadiene, amine = 4-picoline, 3-picoline, 2-picoline, pyridine, 3,5-lutidine or 2,6-lutidine) immobilized on poly(4-vinylpyridine) in contact with water under CO is discussed. Catalytic cycles for these reactions bearing common Rh-H catalytic species are proposed.

Details

ISSN :
15222667 and 09317597
Volume :
38
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi.dedup.....8ece94d5412e31864b7e791b787a2db5
Full Text :
https://doi.org/10.1002/chin.200705270