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Mechanism of the Hydroxycarbonylation of 1-Hexene Catalyzed by Immobilized Rhodium Complexes of Pyridine Ligands
- Source :
- ChemInform. 38
- Publication Year :
- 2007
- Publisher :
- Wiley, 2007.
-
Abstract
- In this work, a mechanistic study of the hydroxycarbonylation of 1-hexene to heptanoic acid and the water gas shift reaction (WGSR) catalyzed by the rhodium(I) complexes, [Rh(COD)(amine)2](PF6) (COD = 1,5-cyclooctadiene, amine = 4-picoline, 3-picoline, 2-picoline, pyridine, 3,5-lutidine or 2,6-lutidine) immobilized on poly(4-vinylpyridine) in contact with water under CO is discussed. Catalytic cycles for these reactions bearing common Rh-H catalytic species are proposed.
Details
- ISSN :
- 15222667 and 09317597
- Volume :
- 38
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi.dedup.....8ece94d5412e31864b7e791b787a2db5
- Full Text :
- https://doi.org/10.1002/chin.200705270