Palladium-Catalyzed Preparation of Silyl Enolates from α,β-Unsaturated Ketones or Cyclopropyl Ketones with Hydrosilanes

Authors :: Yuto Sumida
Hideki Yorimitsu
Koichiro Oshima
Source :: The Journal of Organic Chemistry. 74:7986-7989
Publication Year :: 2009
Publisher :: American Chemical Society (ACS), 2009.
Abstract: Alpha,beta-unsaturated ketones and cyclopropyl ketones undergo palladium-catalyzed hydrosilylation with hydrosilanes to yield (Z)-silyl enolates.

Subjects :: chemistry.chemical_classification
Ketone
Silylation
Hydrosilylation
Organic Chemistry
chemistry.chemical_element
Medicinal chemistry
Chemical synthesis
Catalysis
chemistry.chemical_compound
chemistry
Organic chemistry
Selectivity
Enone
Palladium

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