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Isolation of a highly persistent diphosphanyl radical: the phosphorus analogue of a hydrazyl
- Source :
- Angewandte Chemie: International Edition in English, Vol. 40, No 4 (2001) pp. 723-726
- Publication Year :
- 2001
-
Abstract
- Herein is reported the synthesis and characterization of a [RR1P-PR]-type radical, (I) (R = 2,4,6-tBu3C6H2; R' = CH3). I is stable in the solid state at temps. below -30 Deg. Suitable crystals of I were unobtainable, but a combination of EPR expts. and theor. methods allowed for unambiguous detn. of its structure. [on SciFinder (R)]
- Subjects :
- Redox chemistry
Chemistry
Radical
Phosphorus
Chemistry (all)
Solid-state
Analytical chemistry
chemistry.chemical_element
General Chemistry
Radicals
Medicinal chemistry
Catalysis
Settore FIS/07 - Fisica Applicata(Beni Culturali, Ambientali, Biol.e Medicin)
law.invention
Density functional calculations
EPR spectroscopy
law
Settore BIO/10 - Biochimica
ddc:540
Electron paramagnetic resonance
Subjects
Details
- Language :
- English
- ISSN :
- 05700833
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie: International Edition in English, Vol. 40, No 4 (2001) pp. 723-726
- Accession number :
- edsair.doi.dedup.....916dff04e7058933bf93257358ffe976