Back to Search
Start Over
Investigation of the Coordination Chemistry of a Bisamidinate Ferrocene Ligand with Cu, Ag, and Au
- Source :
- ACS Omega, 7 (5), 4683–4693, ACS Omega, Vol 7, Iss 5, Pp 4683-4693 (2022)
- Publication Year :
- 2021
-
Abstract
- The coordination chemistry of a ferrocene ligand with one bulky amidinate function attached to each ring toward two different coinage metal precursors was investigated. In dependence of the metal and the co-ligands, “ansa” type structures and non-bridged structures were obtained. Six different compounds are reported. In the “ansa” type structures, short Fe–M (M = Cu, Ag) distances were observed in the molecular structures in the solid state. However, theoretical calculations (DFT) did not reveal a stabilizing metal–metal interaction. Instead, dispersion interactions within the ligand and between the ligand and metal seem to represent the main stabilization forces.
- Subjects :
- Chemistry
Chemistry & allied sciences
ddc:540
QD1-999
Subjects
Details
- ISSN :
- 24701343
- Volume :
- 7
- Issue :
- 5
- Database :
- OpenAIRE
- Journal :
- ACS omega
- Accession number :
- edsair.doi.dedup.....91a21930ecaa5c563d483aae6c3a8d7f