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Trapping of Difluorocarbene by Frustrated Lewis Pairs
- Source :
- Angewandte Chemie International Edition. 59:12428-12431
- Publication Year :
- 2020
- Publisher :
- Wiley, 2020.
-
Abstract
- Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho-position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to release difluorocarbene at elevated temperatures.
Details
- ISSN :
- 15213773 and 14337851
- Volume :
- 59
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie International Edition
- Accession number :
- edsair.doi.dedup.....91bddba84e90d7be69f6fc159128f0ce