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Cascade Catalysis for the Homogeneous Hydrogenation of CO2 to Methanol

Authors :
Chelsea A. Huff
Melanie S. Sanford
Source :
Journal of the American Chemical Society. 133:18122-18125
Publication Year :
2011
Publisher :
American Chemical Society (ACS), 2011.

Abstract

This communication demonstrates the homogeneous hydrogenation of CO(2) to CH(3)OH via cascade catalysis. Three different homogeneous catalysts, (PMe(3))(4)Ru(Cl)(OAc), Sc(OTf)(3), and (PNN)Ru(CO)(H), operate in sequence to promote this transformation.

Details

ISSN :
15205126 and 00027863
Volume :
133
Database :
OpenAIRE
Journal :
Journal of the American Chemical Society
Accession number :
edsair.doi.dedup.....934efb9e6f3f765dd373d2e57f4b76f8
Full Text :
https://doi.org/10.1021/ja208760j